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ChemInform Abstract: Simple Route to Chiral Organophosphorus Compounds.

✍ Scribed by O. I. KOLODIAZHNYI; E. V. GRISHKUN

Book ID
112036687
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Simple route to chiral organophosphorus
Simple route to chiral organophosphorus compounds
✍ Oleg I. Kolodiazhnyi; Evgen V. Grishkun πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 176 KB

Reaction of chlorides of nonsymmetrically substituted phosphinic and phosphinous acid with (-)-l,2:3,5-disubstituted-ct-D-glucofuranose proceeds with very high stereoselectivity to give stereochemically pure phosphinic and phosphinous acid esters, which are starting reagents for preparation of chira

nBuLi-Mediated Hydrophosphination: A Sim
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✍ Arnaud Perrier; Virginie Comte; Claude MoΓ―se; Philippe Richard; Pierre Le Gendre πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 493 KB

## Abstract A straightforward synthesis of homoallyl‐ and allylphosphanes has been developed using __n__BuLi‐mediated hydrophosphination of conjugated dienes. In all the cases the phosphorus atom of the reacting phosphane attacked thesterically less demanding side of the diene exclusively. In addit