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Simple Mixed Tricyclohexylphosphane–Triarylphosphite Complexes as Extremely High-Activity Catalysts for the Suzuki Coupling of Aryl Chlorides

✍ Scribed by Robin B. Bedford; Catherine S. J. Cazin; Samantha L. Hazelwood (néeWelch)


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
70 KB
Volume
41
Category
Article
ISSN
0044-8249

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Simple Mixed Tricyclohexylphosphane–Tria
✍ Robin B. Bedford; Catherine S. J. Cazin; Samantha L. Hazelwood (néeWelch) 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 70 KB 👁 1 views

The coupling of aryl halides with aryl boronic acids, the Suzuki reaction (Scheme 1), is one of the most powerful and versatile methods for the synthesis of biaryls. There has recently been considerable interest in the development of new catalysts that can couple aryl chlorides because of the lower