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Extremely High Activity Catalysts for the Suzuki Coupling of Aryl Chlorides: The Importance of Catalyst Longevity.

✍ Scribed by Robin B. Bedford; Samantha L. Hazelwood; Michael E. Limmert

Publisher
John Wiley and Sons
Year
2003
Weight
109 KB
Volume
34
Category
Article
ISSN
0931-7597

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Simple Mixed Tricyclohexylphosphane–Tria
Simple Mixed Tricyclohexylphosphane–Triarylphosphite Complexes as Extremely High-Activity Catalysts for the Suzuki Coupling of Aryl Chlorides
✍ Robin B. Bedford; Catherine S. J. Cazin; Samantha L. Hazelwood (néeWelch) 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 70 KB 👁 1 views

The coupling of aryl halides with aryl boronic acids, the Suzuki reaction (Scheme 1), is one of the most powerful and versatile methods for the synthesis of biaryls. There has recently been considerable interest in the development of new catalysts that can couple aryl chlorides because of the lower