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Simple Mechanism for the Dimerization of Ethylene by Gas-Phase CrOH +

✍ Scribed by O’Kane, Patrick T.; Dudley, Timothy J.

Book ID
120029971
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
787 KB
Volume
32
Category
Article
ISSN
0276-7333

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Reaction of the copper dimer, Cu2 with e
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✍ Li Lian; Farah Akhtar; Peter A. Hackett; David M. Rayner 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 461 KB

The gas-phase kinetics of the reaction between Cuz and C2H4 have been studied as a function of pressure in a fast-flow reactor. The limiting low-pressure, third-order rate constant for the reaction was found to be (9.3 + I .4) x 1 Oew cm6 s-' in He. Modeling studies of this rate constant imply that