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Gas Phase Decomposition by the Lindemann Mechanism

โœ Scribed by S. L. Cole and J. W. Wilder


Book ID
123617156
Publisher
Society for Industrial and Applied Mathematics
Year
1991
Tongue
English
Weight
188 KB
Volume
51
Category
Article
ISSN
0036-1399

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The gas-phase decomposition of methylsil
โœ B. A. Sawrey; H. E. O'Neal; M. A. Ring; D. Coffey Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 738 KB

The gas-phase decompositions of methylsilane and methylsilane-d3 have been investigated in a single-pulse shock tube at 4700 torr total pressure in the temperature range of 1125-1250 K. For CH3SiD3 at 1200 K three primary steps occur in the homogeneous decomposition with efficiencies in parentheses: