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Simple Construction of Bicyclo[4.3.0]nonane, Bicyclo[3.3.0]octane, and Related Benzo Derivatives by Palladium-Catalyzed Cycloalkenylation

โœ Scribed by Toyota, Masahiro; Ilangovan, Andivelu; Okamoto, Rei; Masaki, Tomohito; Arakawa, Makoto; Ihara, Masataka


Book ID
126434786
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
70 KB
Volume
4
Category
Article
ISSN
1523-7060

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Radical cascade reactions of methylenecy
โœ Kurt G. Pike; Christine Destabel; Mike Anson; Jeremy D. Kilburn ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

1,2 Disubstituted methylenecyclopropyl bromides, 6 and 11, undergo radical cascade reactions, involving cyclisation, ring-opening and further cyclisation, to give cis bicyclic products in 67% and 41% yields respectively.