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Radical cascade reactions of methylenecyclopropane derivatives - synthesis of cis-fused bicyclo-3.4.0-nonanes and bicyclo-4.4.0-decanes

✍ Scribed by Kurt G. Pike; Christine Destabel; Mike Anson; Jeremy D. Kilburn

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 234 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01188-5

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✦ Synopsis

1,2 Disubstituted methylenecyclopropyl bromides, 6 and 11, undergo radical cascade reactions, involving cyclisation, ring-opening and further cyclisation, to give cis bicyclic products in 67% and 41% yields respectively.

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