✦ LIBER ✦

Silylation of triacylglycerol: an easy route to new biosiloxanes

✍ Scribed by Abdelkrim El Kadib; Annie Castel; Fabien Delpech; Pierre Rivière

Book ID: 108091330
Publisher: Elsevier Science
Year: 2007
Tongue: English
Weight: 263 KB
Volume: 148
Category: Article
ISSN: 0009-3084
DOI: 10.1016/j.chemphyslip.2007.05.002

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reaction of N-trimethyl silyl amides wit

Reaction of N-trimethyl silyl amides with acid chlorides. an easy synthetic route to nitriles.

✍ Manfred L. Hallensleben 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 140 KB

Silyl-cupration of allene. A new route t

Silyl-cupration of allene. A new route to silylated synthons

✍ P. Cuadrado; A.M. González; F.J. Pulido; Ian Fleming 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 131 KB

Silyl-cupration of allene followed by treatment with iodine anomalously gives the vinyl iodide 2, a versatile synthetic intermediate. Recently, we reported the synthesis of allylsilanes and vinylsilanes by silyl-cupration of allenes with lithium bis(phenyldimethylsilyl)cuprate.

An easy access to α,β-unsaturated thioac

An easy access to α,β-unsaturated thioacylsilanes: a useful route to silylated 1,2-dithiins

✍ Antonella Capperucci; Alessandro Degl'Innocenti; Simona Biondi; Tiziano Nocentin 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 229 KB

Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl 2 •6H 2 O affords an easy and high yielding access to a,b-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products.

An Easy Access to α,β-Unsaturated Thioac

An Easy Access to α,β-Unsaturated Thioacylsilanes: A Useful Route to Silylated 1,2-Dithiins.

✍ Antonella Capperucci; Alessandro Degl'Innocenti; Simona Biondi; Tiziano Nocentin 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 138 KB

New and easy route to primary cyclopropy

New and easy route to primary cyclopropylamines from nitriles

✍ Bertus, Philippe; Szymoniak, Jan 📂 Article 📅 2001 🏛 Royal Society of Chemistry 🌐 English ⚖ 83 KB

An easy route to 11-hydroxy-eudesmanolid

An easy route to 11-hydroxy-eudesmanolides. Synthesis of (±) decipienin A

✍ F. Javier Moreno-Dorado; Francisco M. Guerra; F. Javier Aladro; Jesús M. Bustama 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 895 KB

The preparation of 1 l-hydroxy-eudesmanolides with the stereochemistry found in the Umbelliferae family of plants is described. The decalin system of the eudesmane skeleton is produced by the addition of 5-methyl-2furyllithium to 3-ethoxycyclohex-2-enone and acidic treatment of the resulting adduct.