𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Silyl-cupration of allene. A new route to silylated synthons

✍ Scribed by P. Cuadrado; A.M. González; F.J. Pulido; Ian Fleming

Book ID
104217497
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
131 KB
Volume
29
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Silyl-cupration of allene followed by treatment with iodine anomalously gives the vinyl iodide 2, a versatile synthetic intermediate.

Recently, we reported the synthesis of allylsilanes and vinylsilanes by silyl-cupration of allenes with lithium bis(phenyldimethylsilyl)cuprate.

📜 SIMILAR VOLUMES

ChemInform Abstract: A New Route to Prep
ChemInform Abstract: A New Route to Preparations of Silyl Ethers by Reactions of Silyl Triflimides with Alcohol or Ether.
✍ Zi-Long Tang 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 22 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v