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An Easy Access to α,β-Unsaturated Thioacylsilanes: A Useful Route to Silylated 1,2-Dithiins.

✍ Scribed by Antonella Capperucci; Alessandro Degl'Innocenti; Simona Biondi; Tiziano Nocentini; Giuseppe Rinaudo


Publisher
John Wiley and Sons
Year
2003
Weight
138 KB
Volume
34
Category
Article
ISSN
0931-7597

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An easy access to α,β-unsaturated thioac
✍ Antonella Capperucci; Alessandro Degl'Innocenti; Simona Biondi; Tiziano Nocentin 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 229 KB

Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl 2 •6H 2 O affords an easy and high yielding access to a,b-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products.

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