Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl 2 •6H 2 O affords an easy and high yielding access to a,b-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products.
✦ LIBER ✦
An Easy Access to α,β-Unsaturated Thioacylsilanes: A Useful Route to Silylated 1,2-Dithiins.
✍ Scribed by Antonella Capperucci; Alessandro Degl'Innocenti; Simona Biondi; Tiziano Nocentini; Giuseppe Rinaudo
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 138 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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