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Silver(I)-Catalyzed Deprotection of p -Methoxybenzyl Ethers: A Mild and Chemoselective Method

✍ Scribed by Kern, Nicolas; Dombray, Thomas; Blanc, Aurélien; Weibel, Jean-Marc; Pale, Patrick

Book ID
115484658
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
564 KB
Volume
77
Category
Article
ISSN
0022-3263

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The magnesium bromide diethyl etherate (MgBr2.OEh)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of pmethoxybenzyl (PMB) ether in the presence of 1,3-diene, t-butyldimethylsilyl (TBDMS) ether, benzoate, benzyl ether and acetonide.

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