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ChemInform Abstract: A Mild and Selective Deprotection of p-Methoxybenzyl (PMB) Ether by Magnesium Bromide Diethyl Etherate-Methyl Sulfide.

✍ Scribed by T. ONODA; R. SHIRAI; S. IWASAKI

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199724072

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A Simple Method for the Selective Deprotection of p-Methoxybenzyl Ethers by Cerium(III) Chloride Heptahydrate and Sodium Iodide. -Highly selective deprotection of a variety of p-methoxybenzyl ethers is achieved under mild conditions with CeCl 3 •7H 2 O as promoter and NaI as trapping agent in good t