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Silver-Catalyzed Stereoselective [3+2] Cycloadditions of Cyclopropyl-Indanimines with Carbonyl Compounds

โœ Scribed by Hung, Hsiao-Hua; Liao, Yi-Ching; Liu, Rai-Shung

Book ID
127239903
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
439 KB
Volume
355
Category
Article
ISSN
1615-4150

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[3+2] Cycloaddition Reaction of Cyclopro
[3+2] Cycloaddition Reaction of Cyclopropyl Ketones with Alkynes Catalyzed by Nickel/Dimethylaluminum Chloride
โœ Takashi Tamaki; Dr. Masato Ohashi; Prof. Sensuke Ogoshi ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 328 KB ๐Ÿ‘ 1 views

de reagents. The key to success is the organoaluminum reagents, which activate the carbonyl group of cyclopropyl ketones and stabilize the reaction intermediates. This reaction provides a new method for the synthesis of cyclopentene derivatives. Additional studies to elucidate the reaction mechanism