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Silver-Catalyzed Benzylation and Allylation of Tertiary Alkyl Bromides with Organozinc Reagents

โœ Scribed by Yukihiro Mitamura; Yoshihiro Asada; Kei Murakami; Hidenori Someya; Hideki Yorimitsu; Koichiro Oshima

Book ID
112006001
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
263 KB
Volume
5
Category
Article
ISSN
1861-4728

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Alkylations of Functionalized Organozinc Reagents with Allylic Epoxides Catalyzed by a Cyanocuprate. -Transmetalation of the title reagents with either LiCuCN(Me) or Li2CuCN(Me)2 affords a cyanocuprate which selectively transfers the zinc substituents to allylic epoxides, thus establishing a novel