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ChemInform Abstract: Silver-Catalyzed Benzylation and Allylation of Tertiary Alkyl Bromides with Organozinc Reagents.

โœ Scribed by Yukihiro Mitamura; Yoshihiro Asada; Kei Murakami; Hidenori Someya; Hideki Yorimitsu; Koichiro Oshima


Publisher
John Wiley and Sons
Year
2010
Weight
61 KB
Volume
41
Category
Article
ISSN
0931-7597

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Alkylations of Functionalized Organozinc Reagents with Allylic Epoxides Catalyzed by a Cyanocuprate. -Transmetalation of the title reagents with either LiCuCN(Me) or Li2CuCN(Me)2 affords a cyanocuprate which selectively transfers the zinc substituents to allylic epoxides, thus establishing a novel