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ChemInform Abstract: Silver-Catalyzed, Manganese-Mediated Allylation and Benzylation Reactions of Aldehydes and Ketones.

โœ Scribed by Nicholas T. Barczak; Elizabeth R. Jarvo

Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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Manganese-Mediated Reactions in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes. -The allylation of aldehydes mediated by manganese in water in the presence of a catalytic amount of copper shows exclusive selectivity toward aromatic aldehydes. Aliphatic aldehydes are