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ChemInform Abstract: Manganese-Mediated Reactions in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes.

✍ Scribed by C.-J. LI; Y. MENG; X.-H. YI; J. MA; T.-H. CHAN

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Manganese-Mediated Reactions in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes. -The allylation of aldehydes mediated by manganese in water in the presence of a catalytic amount of copper shows exclusive selectivity toward aromatic aldehydes. Aliphatic aldehydes are inert under the reaction conditions. A complete chemoselectivity toward aromatic aldehydes is also found in the pinacol coupling mediated by manganese. -(LI, C.-

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ChemInform Abstract: Manganese-Mediated
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