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InCl3/Al-Mediated Pinacol Coupling Reactions of Aldehydes and Ketones in Aqueous Media.

โœ Scribed by Chunyan Wang; Yuanjiang Pan; Anxin Wu

Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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Manganese-Mediated Reactions in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes. -The allylation of aldehydes mediated by manganese in water in the presence of a catalytic amount of copper shows exclusive selectivity toward aromatic aldehydes. Aliphatic aldehydes are