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ChemInform Abstract: Zn/InCl3-Mediated Pinacol Cross-Coupling Reactions of Aldehydes with α,β-Unsaturated Ketones in Aqueous Media.

✍ Scribed by Yong-Sheng Yang; Zhi-Liang Shen; Teck-Peng Loh


Publisher
John Wiley and Sons
Year
2009
Weight
34 KB
Volume
40
Category
Article
ISSN
0931-7597

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Manganese-Mediated Reactions in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes. -The allylation of aldehydes mediated by manganese in water in the presence of a catalytic amount of copper shows exclusive selectivity toward aromatic aldehydes. Aliphatic aldehydes are