๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Silicon-directed Nazarov cyclizations. 8. Stereoelectronic control of torquoselectivity

โœ Scribed by Denmark, Scott E.; Wallace, Michael A.; Walker, Christopher B.


Book ID
120486540
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
370 KB
Volume
55
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Silicon-Directed Nazarov Cyclizations. P
โœ Scott E. Denmark; Gary A. Hite ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 829 KB

Minimized strain energies: cis-2j 19.22 kcal/mol, trans-2j 18.14 kcal/mol. In this larger-scale experiment, a significant amount of cis -2i suffered protiodesilylation to cis-2j (H-C(2) at 4.25 ppm (&I) which could not be separated from trans-2j.