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Silicon-Based Cross-Coupling Reactions in the Total Synthesis of Natural Products

✍ Scribed by Scott E. Denmark; Jack H.-C. Liu


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
464 KB
Volume
49
Category
Article
ISSN
0044-8249

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## Abstract Regioselective Suzuki cross‐coupling reactions of tetrabromoselenophene allow a convenient synthesis of aryl‐substituted selenophenes. High yields were obtained using a novel biaryl‐monophosphine ligand. The first tetra(1‐alkynyl)selenophene was prepared in one step by a Sonogashira rea