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The Total Syntheses of Phorboxazoles—New Classics in Natural Product Synthesis

✍ Scribed by Lars Ole Haustedt; Ingo V. Hartung; H. M. R. Hoffmann

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
305 KB
Volume
42
Category
Article
ISSN
0044-8249

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Scheme 5. Domino cyclization to construct the pentacyclic core of cribrostatin 4 (1): a) n-C 6 H 13 SH, TFA/TFE 1:100, 93 %; b) Swern oxidation; c) TBAF, AcOH, THF; d) MeSO 3 H (0.01 % by volume, c = 0.01 m), CH 2 Cl 2 , 51 % (for 3 steps). TFA = trifluoroacetic acid, TFE = trifluoroethanol.