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Short-lived manganate(VI) and manganate(V) intermediates in the permanganate oxidation of sulfite ion

โœ Scribed by Simandi, Laszlo I.; Jaky, Miklos; Schelly, Z. A.


Book ID
121190031
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
281 KB
Volume
106
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of formation of m
โœ Ali M. Shaker ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 169 KB ๐Ÿ‘ 1 views

## Abstract Kinetics and mechanism of the disproportionation of MnO~4~^โˆ’^ via [CMCโ€”Mn^VI^O~4~^2โˆ’^] intermediate complex formation during the oxidation of carboxymethyl cellulose (CMC) polysaccharide have been investigated spectrophotometrically at pH โ‰ฅ12 and various temperatures (15โ€“35^ยฐ^C). The ra