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Alkali-metal-ion, temperature, and pressure effects on the rate of electron transfer between manganate(VI) and permanganate(VII) ions in alkaline aqueous solution

โœ Scribed by Spiccia, Leone; Swaddle, Thomas W.


Book ID
126838613
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
975 KB
Volume
26
Category
Article
ISSN
0020-1669

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Anomalously large effects of pressure on
โœ T.W. Swaddle; L. Spiccia ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science โš– 254 KB

The classical Stranks-Hush-Marcus theory of pressure effects on the rates of outer-sphere electron transfer reaction rates in solution underestimates IzaV\*[; specifically, for the MnO4/MnO24 (aq) exchange, zaV\*=-21.2 (observed) vs. -6.6cm 3 mol 1 (calculated). This discrepancy can best be resolved