Kinetics of the permanganate oxidation of endo-dicyclopentadiene in nonaqueous organic solution. Formation and detection of the manganate(V) ester intermediate
โ Scribed by Ogino, Toshio; Hasegawa, Koichi; Hoshino, Etsuko
- Book ID
- 127257039
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 455 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The absorption spectrwn of a stable organomanganese iratemediate in the homogeneously catalyaed pemangamzte oxkkrtion of endo-d~cyctopentadiene in a non-aqueous system W8 directly determined. The formation and the decompositim of the intermediate mre monitored by folZoting the changes of ab8orbances
## Abstract Kinetics and mechanism of the disproportionation of MnO~4~^โ^ via [CMCโMn^VI^O~4~^2โ^] intermediate complex formation during the oxidation of carboxymethyl cellulose (CMC) polysaccharide have been investigated spectrophotometrically at pH โฅ12 and various temperatures (15โ35^ยฐ^C). The ra
## Abstract The kinetics of formation of the [PVA. Mn^VI^O] intermediate complex have been measured by the conventional spectrophotometric technique. The rate of formation of the complex was found to be given by the expression d[Complex]/d__t__ = __k__~1~[MnOโ~4~][PVA^โ^]. The results showed that t