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Short Formal Synthesis of (−)-Platencin

✍ Scribed by Konrad Tiefenbacher; Johann Mulzer

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
286 KB
Volume
47
Category
Article
ISSN
0044-8249

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Formal Total Synthesis of Platencin
Formal Total Synthesis of Platencin
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## Abstract **The right bicycle**: A concise formal synthesis of platencin was based on an efficient oxygen‐mediated palladium‐catalyzed cycloalkenylation of **1** to form a bicyclo[3.2.1]octane, and a deoxygenative rearrangement of tosylhydrazone **2** to construct the bicyclo[2.2.2]octane **3**.

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## Abstract **Der richtige Bicyclus**: Die effiziente sauerstoffvermittelte palladiumkatalysierte Cycloalkenylierung von **1** zu einem Bicyclo[3.2.1]octan und die desoxygenierende Umlagerung des Tosylhydrazons **2** zum Bicyclo[2.2.2]octan **3** sind wesentliche Schritte der Synthese der Kernstruk

Total Synthesis of (±)-Platencin
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The evolution of bacteria with resistance towards clinically used antibiotics requires constant efforts in the search for new antibacterial compounds to target these menacing strains. [1] Recent advances in screening technologies allowed a team of scientists at Merck to develop and employ a target-b

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