✦ LIBER ✦

Shock wave study of the UV spectrum of CF3I

✍ Scribed by L. Brouwer; J. Troe

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 317 KB
Volume: 82
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85094-4

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✦ Synopsis

The UV absorption spectrum and the dissociation rate of CF$ in Ar have been measured in shock waves. For [Ar] = 1.7 X 10m5 mol cmW3, the dissociation rate constant k/[Ar] = 1.5 x 1016 exp(-168 kJ moi-'/RT) cm? mol -l s-l_ The absorption cross section 0 = aF" [tgh(ee/ZT)] 8, = 409 K, A"o = 2370 cm-l t'* exp{-tgb(Be/2T) {[w -vo(T)] /Avo)2)with upay = 8.05 x lo-l9 cm* andve(T) =(38017 -417T/300 K) cm-'.

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