Study of radiation spectrum of gases heated by strong shock waves
โ Scribed by A.A. Kon'kov; V.P. Ionov
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 404 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0017-9310
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๐ SIMILAR VOLUMES
The UV absorption spectrum and the dissociation rate of CF$ in Ar have been measured in shock waves. For [Ar] = 1.7 X 10m5 mol cmW3, the dissociation rate constant k/[Ar] = 1.5 x 1016 exp(-168 kJ moi-'/RT) cm? mol -l s-l\_ The absorption cross section 0 = aF" [tgh(ee/ZT)] 8, = 409 K, A"o = 2370 cm-l
The unimolecular decomposition of methyl nitrite in the temperature range 680-955 K and pressure range 0.64 to 2.0 atm has been studied in shock-tube experiments employing real-time absorption of CW CO laser radiation by the NO product. Computer kinetic modeling using a set of 23 reactions shows tha