✦ LIBER ✦

Shake-up satellites in Hel photoelectron spectra: N2O4 and CH3O

✍ Scribed by D.P. Chong; D.C. Frost; W.M. Lau; C.A. McDowell

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 400 KB
Volume: 90
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83063-7

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✦ Synopsis

Low-lying vacant molccuku orbltals may lead not only to a breakdow of Koopmans'theorem but also to satellite structure m photoelectron spectra.This paper reports examples of the relatiwly infrequent appearance of shake-up satel-Ltes in Hcl photoelecuon spectra, namely those oi N~OJ and CHaNO. An extended version of the HAhl/3 program was used to mtcrpret these spectra.

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