Intense satellite peaks in the carbon 1s photoelectron spectra of Mo2(O2CH)4 and Mo2(O2CCH3)4
β Scribed by P.M. Atha; P.C. Ford; C.D. Garner; A.A. Macdowell; I.H. Hillier; M.F. Guest; V.R. Saunders
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 309 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The C 1s PES of hloz(OzCH)~ and hfo2(02CCH3)4, reported here, show an mtense satelbte peak close to the mam C 1s bne II-us IS assigned, by means of ab mit~o calculations, to a bI (6) + bt (CZpn) transition of the core hole Ion The la& of an mtense satelhte III the 0 1s spectrum IS dncussed.
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Low-lying vacant molccuku orbltals may lead not only to a breakdow of Koopmans'theorem but also to satellite structure m photoelectron spectra.This paper reports examples of the relatiwly infrequent appearance of shake-up satel-Ltes in Hcl photoelecuon spectra, namely those oi N~OJ and CHaNO. An ext
## ABSTRAm Bidentate complexes between [Mo,(O,CCH,)J and suitable diols from the sugar series show Cotton effects around 500 to 450 (CD band I), 400 (II), 350 (III), and 300 nm (IV), and additional effects at still shorter wavelengths. The sign of Cotton effect IV is identical with the sign of the