An unusual route to the isopolymolybdates; Octamolybdate β-[Mo8O26]4− and hexamolybdate [Mo6O19]2−. Reaction of dioxomolybdenum complexes with triphenylphosphonium ylides. Crystal structures of the salts [PPh3CH2COOEt]+2[NH2Et]+2 [Mo8O26]4−, [PPh3CH2COOEt]+2 [Mo6O19]2−, and [PPh3CH2Ph]+2 [Mo6O19]2−

✍ Scribed by Henri Arzoumanian; André Baldy; Richard Lai; América Odreman; Jacques Metzger; Marcel Pierrot

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 634 KB
• Volume: 295
• Category: Article
• ISSN: 0022-328X
• DOI: 10.1016/0022-328x(85)80318-1