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Shake-up and multiplet structure of ESCA satellites of Cu compounds

โœ Scribed by Sven Larsson


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
606 KB
Volume
40
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The ESCA inner shell :;pectra of Cu compounds are investigated theoretically. It is shown that the large satellites appearing for Cu(lI) compounds correspond to shake-up staies which are close to the configuration p5d9 and have the character-


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Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This