Shake-up and multiplet structure of ESCA satellites of Cu compounds
โ Scribed by Sven Larsson
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 606 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The ESCA inner shell :;pectra of Cu compounds are investigated theoretically. It is shown that the large satellites appearing for Cu(lI) compounds correspond to shake-up staies which are close to the configuration p5d9 and have the character-
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Exatiination of the various &r&ions liable to contribute to stetite profiles in X-ray photoelectron spectra of 3d-transition metal compounds is intended Lo show the inadequacy of the monopble selection rule which has been wed to account for the app.zrent conelztion between satellite!; and pammagneti
Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This