Satellite structure has been obsezved at 8 eV and 12 eV below the main metal 2p peaks for compounds of Sc3+ and Ti4+. These futures are attributed to charge transfer "shake-up" transitions (tag + tzg and eg -+ eg respectively). The 8 eV satellites are only found in sulphate complexes of Se3' \_ This
2p and 2s shake-up satellites in solid compounds of 3d ions
β Scribed by B. Wallbank; I.G. Main; C.E. Johnson
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 346 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0368-2048
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KU X-ray photoelectron (ESCA) ,qrectra of the Co 2p levels have been obtained in fnrns-and ci%[Co(NHa)&a ] Cl isomers\_ It is observed that these compounds slowly decompose under X-ray irradiation. A procedure is employed to record real spectra for both the trans and cis isomers without any sighican
Residual size contractions, \(\Delta(3 d), \Delta(4 d)\), and \(\Delta(4 f+5 d)\), in the relevant series ions with the filled \(2 s^{2} 2 p^{6}-3 s^{2} 3 p^{6}-, 3 d^{10} 4 s^{2} 4 p^{6}-, 4 d^{10} 5 s^{2} 5 p^{6}-\), and \(4 f^{14} 5 d^{10} 6 s^{2} 6 p^{6}\)-electron shells have been demonstrated