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Sequential cyclization-silylation reactions of 1,1-disubstituted alkenes catalyzed by a cationic zirconocene complex

✍ Scribed by Gary A. Molander; Christopher P. Corrette


Book ID
108386859
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
230 KB
Volume
39
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Sequential Cyclizat
✍ G. A. MOLANDER; W. H. RETSCH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex. -In the title reaction affording silylated carbocycles the diastereoselectivity can be enhanced by increasing the size of allylic substituents on the substrate. With an appropriate silane, a 1,7 enyne can also be cyc