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Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex

โœ Scribed by Molander, Gary A.; Retsch, William H.


Book ID
126938922
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
299 KB
Volume
119
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Sequential Cyclizat
โœ G. A. MOLANDER; W. H. RETSCH ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex. -In the title reaction affording silylated carbocycles the diastereoselectivity can be enhanced by increasing the size of allylic substituents on the substrate. With an appropriate silane, a 1,7 enyne can also be cyc