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ChemInform Abstract: Total Synthesis of (.+-.)-Epilupinine via an Organoyttrium-Catalyzed Sequential Cyclization/Silylation Reaction.

✍ Scribed by G. A. MOLANDER; P. J. NICHOLS

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Sequential Cyclizat
ChemInform Abstract: Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex.
✍ G. A. MOLANDER; W. H. RETSCH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex. -In the title reaction affording silylated carbocycles the diastereoselectivity can be enhanced by increasing the size of allylic substituents on the substrate. With an appropriate silane, a 1,7 enyne can also be cyc