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ChemInform Abstract: Sequential Cyclization—Silylation Reactions of 1,1-Disubstituted Alkenes Catalyzed by a Cationic Zirconocene Complex.

✍ Scribed by G. A. MOLANDER; C. P. CORRETTE

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Sequential Cyclizat
ChemInform Abstract: Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex.
✍ G. A. MOLANDER; W. H. RETSCH 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Sequential Cyclization/Silylation of Enynes Catalyzed by an Organoyttrium Complex. -In the title reaction affording silylated carbocycles the diastereoselectivity can be enhanced by increasing the size of allylic substituents on the substrate. With an appropriate silane, a 1,7 enyne can also be cyc