✦ LIBER ✦

Separation of mixtures of solvents with wide bore capillary columns connected in series

✍ Scribed by Gerbino, Tomaso C. ;Castello, Gianrico

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 537 KB
Volume: 15
Category: Article
ISSN: 0935-6304
DOI: 10.1002/jhrc.1240150705

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✦ Synopsis

Abstract

The gas chromatographic separation of the components of a complex mixture of industrial solvents, not possible on a single stationary phase owing to coelution of some of the compounds, has been achieved on two serially connected wide bore capillary columns of different polarity.

The analysis of a mixture of twenty five compounds was optimized using the serial gas chromatography theory of Purnell and Williams. The capacity factors of sample components measured with the two columns coupled in series were found to agree with those predicted by theory, regardless of the order in which they were connected.

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