Due to their identical chemical and physical properties, the separation of enantiomers has been considered one of the most difficult challenges in chemistry from both an analytical or a preparative viewpoint. With the development and commercialization of many new or improved chiral stationary phases
Separation of Enantiomeric Irones by Gas-Liquid Chromatography on Modified Cyclodextrins
✍ Scribed by Franz-Josef Marner; Torsten Runge; Wilfried A. König
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- German
- Weight
- 313 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Natural irones found in the essential oil of Iris rhizomes often are mixtures of enantiomers. The separation of all optical isomers of the irones by GLC on modified cyclodextrins and the determination of their composition within different Iris oils is described. The significance for the biosynthesis of the cycloiridals, C~31~‐triterpenoids, which serve as precursors of the irones, is discussed.
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