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Enantiomeric separation of halocarboxylic acids by capillary gas chromatography

✍ Scribed by Koch, E. ;Nicholson, G. J. ;Bayer, E.

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
412 KB
Volume
7
Category
Article
ISSN
0935-6304

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✦ Synopsis

The direct determination of the enantiomeric purity of halocarboxylic acids is described. The method used involves gas chromatographic separation of the corresponding tert-butylamides on deactivated glass or fused-silica capillaries coated with Chirasil-Val. Both the influence of the amide moiety on enantiomeric resolution and tailing, and the r'acemization during formation of the amide derivatives were studied.

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