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Semiclassical theory of microwave optical activity in asymmetric rotors

✍ Scribed by W.R. Salzman


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
851 KB
Volume
143
Category
Article
ISSN
0301-0104

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πŸ“œ SIMILAR VOLUMES


Semiclassical theory of β€œOptical activit
✍ W.R. Salzman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 418 KB

Earlier work on optical activity in pure rotational spectroscopy is generalized to the more realistic model of the asymmetric top. The analog of the Rosenberg dispersion formula for the optical activity parameter, 8, is given for the J= 0 state of an asymmetric top. It involves only the coupling to

Semiclassical theory of β€œoptical activit
✍ W.R. Salzman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 439 KB

The theory of the optical activity of the asymmetric top in pure rotational spectroscopy is extended to near-resonant frequencies, where there is no analog of the Rosenberg dispersion formula except at zero intensity. Since the optical activity effects due to pure rotational motion are expected to b