Semiclassical theory of microwave optical activity near resonance in asymmetric rotors
โ Scribed by W.R. Salzman
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 713 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
The theory of the optical activity of the asymmetric top in pure rotational spectroscopy is extended to near-resonant frequencies, where there is no analog of the Rosenberg dispersion formula except at zero intensity. Since the optical activity effects due to pure rotational motion are expected to b
Earlier work on optical activity in pure rotational spectroscopy is generalized to the more realistic model of the asymmetric top. The analog of the Rosenberg dispersion formula for the optical activity parameter, 8, is given for the J= 0 state of an asymmetric top. It involves only the coupling to