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Semiclassical theory of optical rotation. Application of a closed form solution of the optical activity problem

✍ Scribed by W.R. Salzman

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
648 KB
Volume
15
Category
Article
ISSN
0301-0104

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πŸ“œ SIMILAR VOLUMES

Semiclassical theory of β€œOptical activit
Semiclassical theory of β€œOptical activity” in the asymmetric top: off resonance
✍ W.R. Salzman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 418 KB

Earlier work on optical activity in pure rotational spectroscopy is generalized to the more realistic model of the asymmetric top. The analog of the Rosenberg dispersion formula for the optical activity parameter, 8, is given for the J= 0 state of an asymmetric top. It involves only the coupling to

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The theory of the optical activity of the asymmetric top in pure rotational spectroscopy is extended to near-resonant frequencies, where there is no analog of the Rosenberg dispersion formula except at zero intensity. Since the optical activity effects due to pure rotational motion are expected to b

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A semiempirical theory of the optical activity of saccharides
✍ Eugene S. Stevens; Banlacore K. Sathyanarayana πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 787 KB

A semiempirical theory of optical activity of saccharides is developed that (a) goes beyond previous empirical treatments, (b) yields calculated Nan rotations which correlate well with experimental data, and (c) accounts for a characteristic c.d. band observed for polysaccharides in the vacuum U.V.