The electrochemical behaviour of the [Co 2 (CO) 6 ] 2 (µ-R-CϵC-through-space and through-bond interactions are operating with different relative weight depending on the spacer L. L-CϵC-R) and [Co 2 (CO) 4 (dppm)] 2 (µ-R-CϵC-L-CϵC-R) series is reported. Qualitative evidence suggests that both
Self-association of Co2+ — Nucleotide and Co2+ — Dinucleotide complexes
✍ Scribed by Jacques Bolard; Geneviève Chottard
- Book ID
- 118310878
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 247 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0006-291X
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📜 SIMILAR VOLUMES
The geometricsand stabiliticsof the Li-CO2 and Na--CO? tomplcxes arc calculated using the self-consistent-field Hartree-Fock method. The minimum energy, Czv strutures of G-CO2 ;Ind Nil-CO2 are found to bc stnblc, by 0.85 and 0.34 cV, respectively, with rcspcct to dissociation to CO2 + alkali atom.
The electrostatic complex of Co+ with a single CO2 molecule is studied by optical excitation of a 3d74s-3d8 transition centered on the metal ion. Excited-state vibrational information is used to characterize the diabatic molecular potential in terms of spectroscopic constants. Two vibrational freque