## Abstract For Abstract see ChemInform Abstract in Full Text.
Carbonylations with CO/H2O and CO/H2 catalyzed by Co2(CO)8-1,2-BIS(diphenylphosphino)ethane complexes
β Scribed by Kazuhisa Murata; Akio Matsuda; Takashi Masuda
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 761 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
Unsaturated ketones and aldehydes were selectively reduced to the corresponding saturated carbonyl compounds by Co 2 (CO) 8 -H 2 O system. The current reducing system also offered a chemoselective reduction of less substituted unsaturated carbonyl groups.
The kinetics of CO and H 2 oxidation over a CuO-CeO 2 catalyst were simultaneously investigated under reaction conditions of preferential CO oxidation (PROX) in hydrogen-rich mixtures with CO 2 and H 2 O. An integral packed-bed tubular reactor was used to produce kinetic data for power-law kinetics