## Abstract For Abstract see ChemInform Abstract in Full Text.
✦ LIBER ✦
Selective 1,4-reduction of unsaturated carbonyl compounds using Co2(CO)8–H2O
✍ Scribed by Hee-Yoon Lee; Mihyun An
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 384 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Unsaturated ketones and aldehydes were selectively reduced to the corresponding saturated carbonyl compounds by Co 2 (CO) 8 -H 2 O system. The current reducing system also offered a chemoselective reduction of less substituted unsaturated carbonyl groups.
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A combination of aluminium and nickel chloride in THF has been shown to effect the selective reduction of the olefinic double bond of the d-enone system. Isolated double bonds and aliphatic carbonyls remain unaffected under these conditions. However, aromatic aldehydes and ketones are converted to t