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A simple procedure for selective reduction of α,β-unsaturated carbonyl compounds using Al-NiCl2 system

✍ Scribed by Manoj J. Hazarika; Nabin C. Barua

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
187 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

A combination of aluminium and nickel chloride in THF has been shown to effect the selective reduction of the olefinic double bond of the d-enone system. Isolated double bonds and aliphatic carbonyls remain unaffected under these conditions. However, aromatic aldehydes and ketones are converted to the corresponding hydroxy compounds by this system in good yields.

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