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Self-Assembly of a Dimeric Porphyrin Host

✍ Scribed by Dr. Christopher A. Hunter; Luke D. Sarson

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
410 KB
Volume
33
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

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The synthesis of phthalocyanines 1a and 1b appended with four glycoluril modules is presented. 1 H NMR spectroscopy showed that 1a and 1b self-assemble by means of hydrogen bonding to form discrete dimers. Capsule formation is solvent dependent where the dimeric assembly is most pronounced in aromat

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We have synthesized a family of receptors for flavins based on 6-aryl-2,4-acyldiamino-s-triazines. In these synthetic hosts, systematic variation of the position and functionalization of a hydrogen bond-donating amide moiety on the 6-aryl ring modulates dimerization over a 17-fold range, and flavin