✦ LIBER ✦
Control of host dimerization and flavin recognition via intramolecular receptor self-assembly
✍ Scribed by Eunhee Jeoung; Hugues Augier de Cremiers; Robert Deans; Graeme Cooke; Sarah L. Heath; Petra E. Vanderstraeten; Vincent M. Rotello
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 128 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
We have synthesized a family of receptors for flavins based on 6-aryl-2,4-acyldiamino-s-triazines. In these synthetic hosts, systematic variation of the position and functionalization of a hydrogen bond-donating amide moiety on the 6-aryl ring modulates dimerization over a 17-fold range, and flavin recognition over a 7-fold range.