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A self-assembled phthalocyanine dimer

✍ Scribed by Arne Lützen; Stephen D Starnes; Dmitry M Rudkevich; Julius Rebek Jr.


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
163 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of phthalocyanines 1a and 1b appended with four glycoluril modules is presented. 1 H NMR spectroscopy showed that 1a and 1b self-assemble by means of hydrogen bonding to form discrete dimers. Capsule formation is solvent dependent where the dimeric assembly is most pronounced in aromatic solvents.


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